Author: Lau, Mei Tung
Title: Organic thermoelectric materials from conducting metallopolymers
Advisors: Wong, Wai-yeung Raymond (ABCT)
Degree: Ph.D.
Year: 2022
Subject: Thermoelectric materials
Polymers -- Electric properties
Hong Kong Polytechnic University -- Dissertations
Department: Department of Applied Biology and Chemical Technology
Pages: xxxvii, 263 pages : color illustrations
Language: English
Abstract: Seven different polymers with planar or strongly-interacting structure (PtTDPP16C, FFDPPS, FFDPPT, PtTPY1TPY, PtTPY2TPY, PtCC4H9 and CuCC4H9), twelve conjugated radical-containing metallopolymers (FFTEMPOS, FFTEMPOT,FTEMPOS, FFTPATEMPOS, FFTPATEMPOT, FTPATEMPOS, FFTTEMPOS, FFTTEMPOT, FTTEMPOS, FFCzTEMPOS, FFCzTEMPOT and FCzTEMPOS), three non-conjugated radical-containing polymers (FcCF4TBNO, FcCF5CONO, and FcCOOTEMPONO) and five chemically functionalized single-walled carbon nanotubes (SWCNT-Pt(PBu3)2-phenyl, SWCNT-Pt(PBu3)2-TPA, SWCNT-Pt(PBu3)2-TPE, SWCNT-Pt(PBu3)2-carbazole and SWCNT-Pt(PBu3)2-porphyrin) were synthesized. Their photophysical, electrochemical, thermoelectric properties (including electrical conductivity (σ), Seebeck coefficient (S) and power factor (PF)) and morphologies have been studied.
Rights: All rights reserved
Access: open access

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