Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor | Department of Civil and Structural Engineering | en_US |
| dc.creator | Yang, Dong | - |
| dc.identifier.uri | https://theses.lib.polyu.edu.hk/handle/200/5991 | - |
| dc.language | English | en_US |
| dc.publisher | Hong Kong Polytechnic University | - |
| dc.rights | All rights reserved | en_US |
| dc.title | Oxidation of 2, 4-dichlorophenol by persulfate activated by Fe⁰ | en_US |
| dcterms.abstract | 2, 4-dichlorophenol (2, 4-DCP) is a commonly used chemical especially in the manufacture of other pesticide products and pharmaceuticals. Effluents of wastewater containing 2, 4-DCP are ecological hazards and they must be properly treated before discharged into the environment. This dissertation investigated the feasibility of degradation of 2, 4-DCP using persulfate as an oxidant and zero-valent iron as a catalyst in the laboratory. The effects of main factors, including the dosage of zero-valent iron, concentration of persulfate, pH value and presence of some inorganic ions on the efficiency of 2, 4-DCP degradation were investigated and optimized. The experimental result showed that 93% of 2, 4-DCP removal were achieved at the persulfate dosage of 1 mM and iron dosage of 0.025 g/L, with initial concentration of 2, 4-DCP solution at 20 mg/L (0.12 mM) within 3 hours. The experimental results also revealed that persulfate can promote the 2, 4-DCP degradation but excess amount of persulfate can limit the reaction and persulfate alone resulted in little removal of 2, 4-DCP; in acid condition, the removal efficiency increased with the increase of pH and the optimum removal was achieved at pH 6; it can also be found that the presence of anions could inhibit the degradation of 2, 4-DCP and their inhibiting effects can be ranked from low to high in an order of NO₃⁻ < C₁⁻ < C₂O₄²⁻ < H₂PO₄⁻ < HCO₃⁻ < CO₃²⁻. | en_US |
| dcterms.extent | viii, 85 leaves : ill. ; 30 cm. | en_US |
| dcterms.isPartOf | PolyU Electronic Theses | en_US |
| dcterms.issued | 2010 | en_US |
| dcterms.educationalLevel | All Master | en_US |
| dcterms.educationalLevel | M.Sc. | en_US |
| dcterms.LCSH | Hong Kong Polytechnic University -- Dissertations | en_US |
| dcterms.LCSH | Dichlorophenol -- Oxidation | en_US |
| dcterms.LCSH | Persulfates | en_US |
| dcterms.LCSH | Activation (Chemistry) | en_US |
| dcterms.LCSH | Iron | en_US |
| dcterms.accessRights | restricted access | en_US |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| b23604499.pdf | For All Users (off-campus access for PolyU Staff & Students only) | 9.6 MB | Adobe PDF | View/Open |
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